If n2 > n1, then the light is entering an optically more dense medium and the ray will bend "towards the normal" as it enters n2.
Note that the ray bends towards the normal as the light enters the glass and that θglass is smaller than θair.
If n2 < n1, then the light is entering an optically less dense medium and the ray bends "away from the normal" when it enters n2.
This phenomena occurs because the wavelength lengthens in the second medium resulting in the light having a faster average velocity.
Note that the ray bends away from the normal as the light exits the glass as it returns into the air and that θair is greater than θglass.
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